after that Grand Magic Games story arc the union raid skills opened are gray & juvia, juvia&lucy, Erza and kagura, sting & rogue and Wendy and sheeria
After chapter 8
Make jellal your companion , team up with Erza go take the A rank mission and Erza&jellal worked awaken first

Then epilogue: natsu x Lucy union raid and natsu , Gajeel’s union raid and levy x gavel’s union raid

Natsu and gajeel's union raid(Fire Dragon Roar + Iron Dragon Roar
0:02

Lucy and juvia's union raid(Hydro Screw)
0:40

Wendy and sherria's union raid(Landing Sky Arrow/ Trading Sky Arrow)
1:03

Gruvia's Union Raid(Water Nebula / Ice - Make Ice Geyser)
1:15

Natsu and gray's union raid( Brilliant Flame / Gungnir)
1:29

Sabortooth Twin Dragon's union raid(Holy Shadow Dragon Flash Fang)
1:42

Erza and Kagura(sword Sisters) union raid(Sword flash: Union Stance)
2:00

Jerza's union raid( Grand Chariot)
2:19

Nalu's union raid(Phoenix Impact)
2:40

Gajevy's union raid(Iron on ice)
3:03

Erza Scarlet/Mirajane Strauss's Union Raid(Rampant Demonic Blade)
3:40

here's the playlist
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