[ Ссылка ] presents: Alkyne Hydroboration Oxidation: Reaction and Step-by-Step Mechanism using BH3, B2H6, Sia2BH or 9-BBN
📺Watch Next: Chain Elongation - Terminal Alkynes [ Ссылка ]
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This video shows you the reaction and mechanism for the hydroboration oxidation of alkynes, in which an alkyne reacts with a boron-containing reagent, followed by NaOH and H2O2, to form either an aldehyde or ketone product at the less substituted, anti-Markovnikov position.
You’ll learn the step-by-step alkyne hydroboration oxidation mechanism, including Keto Enol Tautomerization to isomerize an unstable enol intermediate in a basic environment.
Finally you’ll learn about the regioselectivity of the reaction and compare the products when starting with terminal, symmetric or asymmetric internal alkynes.
↪ Links & Resources Mentioned In This Video ↩
▸Alkyne Reaction Series + Cheat Sheet [ Ссылка ]
▸Alkene Hydroboration Oxidation [ Ссылка ]
▸Alkene Reaction Shortcuts [ Ссылка ]
▸Alkene Reaction Series + Cheat Sheet [ Ссылка ]
▸Keto Enol Tautomerization [ Ссылка ]
▸Markovnikov’s Rule [ Ссылка ]
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⏱ In this video:
[0:19] Overview of Alkyne Hydroboration
[0:58] Review of Alkene Hydroboration
[2:31] Boron Reagents
[4:44] Mechanism for Alkyne Hydroboration
[9:50] Regioselectivity
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