To unlock the quests for these weapons, you must first do the pre-requirement quests that start with Eintou Madaki in Mountainhome. The quest you want to unlock is called Madaki's Stratagem as this is the quest that you go to obtain the weapon molds. In addition to these quests, you need to have 20 Weapon Mastery in the weapon you wish to craft or the quest will not be offered.

When you have the quest, you are tasked with gathering quest materials to have the NPC craft the weapon for you. Since these are quest materials, you can only start gathering the items once on the quest. Its also not just a simple task, expect to spend a few hours gathering all the materials. After you’ve gathered them all, you turn in the quest and obtain your “legendary” weapon!

This video shows How to Unlock Quest for Legendary Weapons New World
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