Peridot (/ˈpɛrɪdɒt/ or /ˈpɛrɪdoʊ/) (sometimes called chrysolite) is gem-quality olivine and a silicate mineral with the formula of (Mg, Fe)2SiO4. As peridot is a magnesium-rich variety of olivine (forsterite), the formula approaches Mg2SiO4. Its green color is dependent on the iron contents within the structure of the gem. Peridot occurs in silica-deficient rocks such a volcanic basalt as well as in pallasitic meteorites. Peridot is one of only two gems observed to be formed not in the Earth’s crust, but in molten rock of the upper mantle. Gem-quality peridot is rare to find on Earths surface due to its susceptibility to weathering during transportation from deep within the mantle to the surface.

In the Middle Ages, the gemstone was considered a stone that could provide healing powers, curing depression and opening the heart. Peridot is the birthstone for the month of August and the 16 year wedding anniversary gemstone.


Contents
1 Etymology
2 Appearance
3 Mineral Properties
3.1 Crystal structure
3.2 Surface property
4 Occurrence
4.1 Geologically
4.2 In meteorites
5 Gemology
6 Cultural History
7 Gallery
8 References
9 External links
Etymology
The origin of the name peridot is uncertain. The Oxford English Dictionary suggests an alteration of Anglo–Norman pedoretés (classical Latin pæderot-), a kind of opal, rather than the Arabic word faridat, meaning "gem".

The Middle English Dictionary's entry on peridot includes several variations: peridod, peritot, pelidod and pilidod — other variants substitute y for the is seen here.[1]

The earliest use in England is in the register of the St Albans Abbey, in Latin, and its translation in 1705 is possibly the first use of peridot in English. It records that on his death in 1245, Bishop John bequeathed various items, including peridot, to the Abbey.[2]

Appearance
Peridot is one of the few gemstones that occur in only one color: an olive-green. The intensity and tint of the green, however, depends on the percentage of iron in the crystal structure, so the color of individual peridot gems can vary from yellow, to olive, to brownish-green. In rare cases, peridot may have a medium-dark toned, pure green with no secondary yellow hue or brown mask.[3]

Mineral Properties
Crystal structure

The atomic scale structure of olivine looking along the a axis. Oxygen is shown in red, silicon in pink, and magnesium/iron in blue. A projection of the unit cell is shown by the black rectangle.
The molecular structure of peridot consist of isomorphic olivine, silicate, magnesium and iron in an orthorhombic crystal system. In an alternative view, the atomic structure can be described as a hexagonal, close-packed array of oxygen ions with half of the octahedral sites occupied with magnesium or iron ions and one-eighth of the tetrahedral sites occupied by silicon ions.

Surface property
Oxidation of peridot does not occur at natural surface temperature and pressure, but begins to occur slowly at 600°C with rates increasing with temperature.[4] The oxidation of the olivine occurs by initial breakdown of the fayalite component, and subsequent reaction with the forsterite component, to give magnetite and orthopyroxene.

Occurrence
Geologically
Olivine, of which peridot is a type, is a common mineral in mafic and ultramafic rocks, often found in lava and in peridotite xenoliths of the mantle, which lava carries to the surface; however, gem-quality peridot occurs in only a fraction of these settings. Peridots can also be found in meteorites.

Peridots can be differentiated by size and composition. A peridot formed as a result of volcanic activity tends to contain higher concentrations of lithium, nickel and zinc than those found in meteorites.[5]

Olivine is an abundant mineral, but gem-quality peridot is rather rare due to its chemical instability on Earth's surface. Olivine is usually found as small grains and tends to exist in a heavily weathered state, unsuitable for decorative use. Large crystals of forsterite, the variety most often used to cut peridot gems, are rare; as a result olivine is considered to be precious.

In the ancient world, mining of peridot, called topazios then, on St. John's Island in the Red Sea began about 300 B.C.[6]

The principal source of peridot olivine today is the San Carlos Apache Indian Reservation in Arizona.[7] It is also mined at another location in Arizona, and in Arkansas, Hawaii, Nevada, and New Mexico at Kilbourne Hole, in the US; and in Australia, Brazil, China, Egypt, Kenya, Mexico, Myanmar (Burma), Norway, Pakistan, Saudi Arabia, South Africa, Sri Lanka, and Tanzania.

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